Jun is there to make sure things are serious I think, they are going out for over a month and that is probably the longest she ever had.
And he probably noticed a change in Nikaidou's behaviour too, since she stopped responding to his calls before the phone dropped in the bridge.
As for Nikaidou's feelings, she did mention that she gets hot when she kisses Kurumi so I think this muddled feelings drama is just a set up for she actually getting turned on and making a move on Kurumi since I think Kurumi is too much of a sweety to go on the offensive